It depends. First, it should belong to your mother's estate.
Second, please click the following resources for more details.
The form is mainly for information purposes.
If your mother is filing a final 1040NR, see this link for SprinTax to complete the return.
IRS: Foreign Source Income - Form 1042-S Reporting Not Required.
Per 2019 Form 1042-S is for Foreign Person's U.S. Source Income Subject to Withholding Instructions:
Exemption Code 15: Payee not subject to Chapter 4 withholding
Income Code 15: Pensions, annuities, alimony, and/or insurance premiums
Our condolences for your loss.
@fonrilloon